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蓝宇，2003年和2008年在北京大学完成获本科和博士学位，2009年至2012年在美国加州大学洛杉矶分校从事博士后研究。2012年加入必赢线路检测中心独立开展科学研究，历任特聘研究员、教授、博士生导师。现任理论与计算化学重庆市重点实验室主任。蓝宇工作聚焦反应机制调控下的功能分子精准合成。通过对合成反应进行理性设计，实现原理和机制指导的功能分子精准合成。在此领域，近年来以通讯作者（含共同）在包括Nat. Chem.（2篇）、J. Am. Chem. Soc.（22篇）、Angew. Chem. Int. Ed.（30篇）、Nat. Commun.（12篇）、Acc. Chem. Res.（2篇）、Chem（4篇）等期刊上发表学术论文250余篇，累计被他人引用过万次。蓝宇入选“重庆市青年专家工作室”，入选中国青年化学家元素周期表（中国化学会）代言“钽”，入选中国化学会高级会员。蓝宇2018年获国家自然科学基金优秀青年基金资助，曾主持国家自然科学基金项目四项。蓝宇获2016年中国化学会青年化学奖，2018年重庆市自然科学奖一等奖（第一完成人），2018年重庆大学唐立新优秀科研教师奖二等奖。
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联系方式
LanYu@cqu.edu.cn
研究方向
有机光催化反应机制；
机制导向的精准合成；
均相催化反应机制。
代表性论文、专著和专利
近期代表作：
专著
(2) “Computational Methods in Organometallic Catalysis” Lan, Y. WILEY-VCH GmbH, Germany, 2021. (ISBN: 978-3-527-34601-1)
(1) “Computational Advances of Rh-Catalyzed C–H Functionalization” Lan, Y.; Cui, C.-X.; Liu, S.; Li, C.-X.; Bai, R. Springer Nature, Singapore, 2021. (ISBN: 978-981-16-0431-7; DOI: 10.1007/978-981-16-0432-4)
论文
(259) “Nickel-Catalyzed Cross-Redistribution between Hydrosilanes and Silacyclobutanes” Chen, S.; He, X.; Jin, C.; Zhang, W.; Yang, Y.; Liu, S.; Lan, Y.*; Houk, K. N.*; Shen, X.* Angew. Chem. Int. Ed. 2022, 61, e202213431. (DOI: 10.1002/anie.202213431)
(258) “Enantioselective Synthesis of Spirosilabicyclohexenes by Asymmetric Dual Ring Expansion of Spirosilabicyclobutane with Alkynes” Chen, H.; Peng, J.; Pang, Q.; Du, H.; Huang, L.; Gao, L.; Lan, Y.*; Yang, C.*; Song, Z.* Angew. Chem. Int. Ed. 2022, 61, e202212889. (DOI: 10.1002/anie. 202212889)
(257) “The in Vitro Biosynthesis of Chlorophyll b via Enzyme Catalysis” Niu, L.; Lan, Y.* ACS Cent. Sci. 2022, 8, 1373-1375. (DOI: 10.1021/acscentsci.2c00997)
(256) “Catalytic Multicomponent Synthesis of C-Acyl Glycosides by Consecutive Cross-Electrophile Couplings” Jiang, Y.; Yang, K.; Wei, Y.; Wang, Q.*; Li, S.-J.*; Lan, Y.*; Koh, M. J.* Angew. Chem. Int. Ed. 2022, 61, e202211043. (DOI: 10.1002/anie.202211043)
(255) “Structure, reactivity and catalytic properties of manganese-hydride amidate complexes” Wang, Y.; Liu, S.; Yang, H.; Li, H.; Lan, Y.*; Liu, Q.* Nat. Chem. 2022, 14, ASAP. (DOI: 10.1038/s41557-022-01036-6)
(254) “What is the difference between mono- and biphosphine ligands? Revealing the chemoselectivity in Pd-catalysed carbenation of bromonaphthalene” Gong, W.; Fu, D.; Zhong, K.; Ni, H.; He, X.; Shan, C.*; Li, R.*; Lan, Y.* Org. Chem. Front. 2022, 9, 4916-4923. (DOI: 10.1039/d2qo00910b)
(253) “How Strain-Release Determines Chemoselectivity: A Mechanistic Study of Rhodium-Catalyzed Bicyclo[1.1.0]butane Activation” Lai, W.; Zhong, K.*; Liu, S.; Liu, S.; Chen, H.; Ni, H.; Zeng, Z.; Zhao, Z.; Lan, Y.*; Bai, R.* J. Phys. Chem. Lett. 2022, 13, 7694-7701. (DOI: 10.1021/acs.jpclett.2c01528)
(252) “Regio- and Stereoselective 1,2-Oxyhalogenation of Non-Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes” Liu, M.; Sun, J.; Zhang, T.; Ding, Y.; Han, Y.-Q.; Martín-Montero, R.; Lan, Y.*; Shi, B.-F.*; Engle, K. M.* Angew. Chem. Int. Ed. 2022, 61, e202209099. (DOI: 10.1002/anie.202209099)
(251) “Perfluoroarene Interaction-Controlled Chiral Phosphoric Acid-Catalyzed Enantioselective Michael Addition of Difluoroenoxysilanes to Azadienes: a Combination of Experimental and Theoretical Studies” Li, J.; Chen, H.; Zhong, R.; Zhu, L.; Liu, S.; Ding, H.; Yang, J.; Wang, L.; Lan, Y.*; Wang, Z.* ACS Catal. 2022, 12, 9655-9663. (DOI: 10.1021/acscatal.2c01671)
(250) “The chiral pyridoxal-catalyzed biomimetic Mannich reaction: the mechanism and origin of stereoselectivity” Han, L.-L.; Zhang, Q.-Y.; Li, X.; Qiao, Y.*; Lan, Y.*; Wei, D.* Org. Chem. Front. 2022, 9, 4401-4410. (DOI: 10.1039/d2qo00705c)
(249) “Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes” Chen, S.; He, X.; Jin, Y.; Lan, Y.*; Shen, X.* Nat. Commun. 2022, 13, 3691. (DOI: 10.1038/s41467-022-31458-2)
(248) “The regioselectivity of the sulfonylation of tetrazoles: a theoretical view” Liu, C.-C.; Qiao, B.; Qu, L.-B.; Zhang, T.*; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2022, 9, 4009-4015. (DOI: 10.1039/d2qo00797e)
(247) “Iminyl radical-triggered relay annulation for the construction of bridged aza-tetracycles bearing four contiguous stereogenic centers” Jiang, K.; Li, S.-J.; Liu, Q.-P.; Yu, N.; Li, Y.-L.; Zhou, Y.-Q.; He, K.-C.; Lin, J.; Zheng, T.-Y.; Lang, J.; Lan, Y.*; Wei, Y.* Chem. Sci. 2022, 13, 7283-7288. (DOI: 10.1039/d2sc01548j)
(246) “An alternative non-redox Ni(I) pathway in hydroaminomethylation: A theoretical perspective” Qiao, B.; Bai, R.; Zhang, T.*; Li, S.-J.*; Lan, Y.* Mol. Catal. 2022, 526, 112378. (DOI: 10.1016/j.mcat.2022.112378)
(245) “Design and synthesis of stable four-coordinated benzotriazole-borane with tunable fluorescence emission” Tang, Q.; Li, S.-J.; Ye, X.; Yuan, T.; Zhao, K.; He, Y.; Shan, C.; Wojtas, L.; Richardson, D.; Lan, Y.*; Shi, X.* Chem. Sci. 2022, 13, 5982-5987. (DOI: 10.1039/d2sc01103d)
(244) “Visible-light-induced cross-coupling of aryl iodides with hydrazones via an EDA-complex” Pan, P.; Liu, S.; Lan, Y.*; Zeng, H.*; Li, C.-J.* Chem. Sci. 2022, 13, 7165-7171. (DOI: 10.1039/d2sc01909d)
(243) “NHC-Catalyzed Transformation Reactions of Imines: Electrophilic versus Nucleophilic Attack” Liu, C.; Han, P.; Zhang, X.; Qiao, Y.; Xu, Z.; Zhang, Y.; Li, D.; Wei, D.*; Lan, Y.* J. Org. Chem. 2022, 87, 7989-7994. (DOI: 10.1021/acs.joc.2c00621)
(242) “Enantioselective Nickel-Catalyzed Si−C(sp2) Bond Activation and Migratory Insertion to Aldehydes: Reaction Scope and Mechanism” Wang, Q.; Zhong, K.-B.; Xu, H.; Li, S.-N.; Zhu, W.-K.; Ye, F.; Xu, Z.; Lan, Y.*; Xu, L.-W.* ACS Catal. 2022, 12, 4571-4580. (DOI: 10.1021/acscatal.2c00533)
(241) “Palladium-Catalyzed Asymmetric [3 + 2] Annulation of Vinylethylene Carbonates with Alkenes Installed on Cyclic N‑Sulfonyl Imines: Highly Enantio- and Diastereoselective Construction of Chiral Tetrahydrofuran Scaffolds Bearing Three Vicinal and Quaternary Stereocenters” Ke, M.; Qiao, B.; Yu, Y.; Li, X.; Xiao, X.; Li, S.-J.; Lan, Y.*; Chen, F.* J. Org. Chem. 2022, 87, 5166-5177. (DOI: 10.1021/acs.joc.1c03157)
(240) “Boryl Radical Activation of Benzylic C−OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis” Li, W.-D.; Wu, Y.; Li, S.-J.; Jiang, Y.-Q.; Li, Y.-L.; Lan, Y.*; Xia, J.-B.* J. Am. Chem. Soc. 2022, 144, 8551-8559. (DOI: 10.1021/jacs.1c12463)
(239) “Theoretical study on mechanism of cycloaddition reaction between o-alkynylbenzaldoximes and hexynol catalyzed by silver(I)” Yang, X.; Hao, Q.; Li, S.*; Zhu, Y.*; Lan, Y.* Mol. Catal. 2022, 522, 112227. (DOI: 10.1016/j.mcat.2022.112227)
(238) “Regioselectivity of Pd-catalyzed o-carborane arylation: a theoretical view” Liu, J.; Fu, D.; Chen, Z.; Li, T.; Qu, L.-B.; Li, S.-J.*; Zhang, W.*; Lan, Y.* Org. Chem. Front. 2022, 9, 1686-1695. (DOI: 10.1039/d2qo00046f)
(237) “Regiospecific construction of m-alkenyl benzaldehyde from b-bromoenal and vinyl borate” Xin, X.; Liu, Y.; Zhong, L.; Li, Y.; Luo, H.; Liu, L.; Bai, R.; Lan, Y.*; Li, B.* Chem. Commun. 2022, 58, 4989-4992. (DOI: 10.1039/d2cc01441f)
(236) “The Stannum–Ene Reactions of Benzyne and Cyclohexyne with Superb Chemoselectivity for Cyclohexyne” Li, L.; Shan, C.; Shi, J.; Li, W.; Lan, Y.*; Li, Y.* Angew. Chem. Int. Ed. 2022, 61, e202117351. (DOI: 10.1002/anie.202117351)
(235) “Ligand-Controlled Site- and Enantioselective Carbene Insertion into Carbon-Silicon Bonds of Benzosilacyclobutanes” Huo, J.; Zhong, K.; Xue, Y.; Lyu, M.; Ping, Y.; Ouyang, W.; Liu, Z.; Lan, Y.*; Wang, J.* Chem. Eur. J. 2022, 28, e202200191. (DOI: 10.1002/chem.202200191)
(234) “Diradical Generation via Relayed Proton-Coupled Electron Transfer” Shi, Q.; Pei, Z.; Song, J.; Li, S.-J.; Wei, D.*; Coote, M. L.*; Lan, Y.* J. Am. Chem. Soc. 2022, 144, 3137-3145. (DOI: 10.1021/jacs.1c12360)
(233) “Mechanistic Investigation of Cu-Catalyzed Asymmetric Alkynylation of Cyclic N‑Sulfonyl Ketimines with Terminal Alkynes” Zeng, Z.; Yan, F.; Dai, M.; Yu, Z.; Liu, F.; Zhao, Z.; Bai, R.*; Lan, Y.* Organometallics 2022, 41, 270-277. (DOI: 10.1021/acs.organomet.1c00624)
(232) “Mechanistic investigation of zwitterionic MOF-catalyzed enyne annulation using UNLPF-14-MnIII as catalyst” Liu, T.; Duan, R.; Wang, Y.; Li, S.; Qu, L.; Song, J.*; Liu, Q.*; Lan, Y.* Chin. Chem. Lett. 2022, 33, 4281-4286. (DOI: 10.1016/j.cclet.2022.01.041)
(231) “Chemo-, regio- and enantioselective dearomative (3+2) reaction of non-functionalized 1-naphthols” Mei, G.-J.*; Luo, Y.; Koay W. L.; Li, R.; Lan, Y.*; Lu, Y.* Chem Catal. 2022, 2, 386-399. (DOI: 10.1016/j.checat.2021.12.012)
(230) “Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes” He, Y.; Wang, Y.; Li, S.-J.; Lan, Y.*; Wang, X.* Angew. Chem. Int. Ed. 2022, 61, e202115497. (DOI: 10.1002/anie.202115497)
(229) “Experimental and Computational Studies on the Directing Ability of Chalcogenoethers in Palladium-Catalyzed Atroposelective C-H Olefination and Allylation” Liao, G.; Zhang, T.; Jin, L.; Wang, B.-J.; Xu, C.-K.; Lan, Y.*; Zhao, Y.*; Shi, B.-F.* Angew. Chem. Int. Ed. 2022, 61, e202115221. (DOI: 10.1002/anie.202115221)
(228) “Carbene-Enabled Ether Activation Through the Formation of Oxonium: A Theoretical View” Wang, Y.-N.; Wang, X.; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2022, 9, 1247-1253. (DOI: 10.1039/D1QO01730F)
(227) “Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design” Duan, M.; Díaz-Oviedo, C. D.; Zhou, Y.; Chen, X.; Yu, P.; List, B.*; Houk, K. N.*; Lan, Y.* Angew. Chem. Int. Ed. 2022, 61, e202113204. (DOI: 10.1002/anie.2020113204)
(226) “Is the metal involved or not? A computational study of Cu(I)-catalyzed [4 + 1] annulation of vinyl indole and carbene precursor” He, X.; Zhong, K.; Heng, D.; Zeng, Z.; Ni, H.; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2022, 33, 2031-2035. (DOI: 10.1016/j.cclet.2021.10.010)
(225) “Insights into Organoamine-Catalyzed Asymmetric Synthesis of Axially Chiral Allenoates Using Morita−Baylis−Hillman Carbonates and Trisubstituted Allenoates: Mechanism and Origin of Stereoselectivity” Zhang, J.; Luo, J.; Li, X.; Zhang, Q.; Wu, Z.; Lan, Y.*; Wei, D.* J. Org. Chem. 2021, 86, 15276-15283. (DOI: 10.1021/acs.joc.1c01871)
(224) “Asymmetric Construction of Tertiary/Secondary Carbon-Phosphorus Bonds via Bifunctional Phosphonium Salt Catalyzed 1,6-Addition” Chen, Y.; Yu, Z.; Jiang, Z.; Tan, J.-P.; Wu, J.-H.; Lan, Y.*; Ren, X.; Wang, T.* ACS Catal. 2021, 11, 14168-14180. (DOI: 10.1021/acscatal.1c03149)
(223) “Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation” Yang, B.; Li, S.-J.; Wang, Y.*; Lan, Y.*; Zhu, S.* Nat. Commun. 2021, 12, 5257. (DOI: 10.1038/s41467-021-25594-4)
(222) “On the Me chanism of Cu Catalyzed Hydroboraethylation of Isocyanates” Huang, L.; Wang, Y.; Liu, J.; Li, S.*; Zang, W.*; Lan, Y.* Chin. J. Org. Chem. 2021, 41, 4347-4352. (DOI: 10.6023/cjoc202107031)
(221) “Visible-light photoredox-catalyzed selective carboxylation of C(sp3)-F bonds with CO2” Yan, S.-S.; Liu, S.-H.; Chen, L.; Bo, Z.-Y.; Jing, K.; Gao, T.-G.; Yu, B.; Lan, Y.*; Luo, S.-P.; Yu, D.-G.* Chem 2021, 7, 3099-3113. (DOI: 10.1016/j.chempr.2021.08.004)
(220) “Practical DMSO-promoted selective hydrolysis–oxidation of lignocellulosic biomass to formic acid attributed to hydrogen bonds” Guo, Y.-J.; Li, S.-J.; Sun, Y.-L.; Wang, L.; Zhang, W.-M.; Zhang, P.; Lan, Y.*; Li, Y.* Green Chem. 2021, 23, 7041-7052. (DOI: 10.1039/D1GC02265B)
(219) “Palladium-Catalyzed Enantioselective Carbene Insertion into Carbon−Silicon Bonds of Silacyclobutanes” Huo, J.; Zhong, K.; Xue, Y.; Lyu, M.; Ping, Y.; Liu, Z.; Lan, Y.*; Wang, J.* J. Am. Chem. Soc. 2021, 143, 12968-12973. (DOI: 10.1021/jacs.1c05879)
(218) “Oxymetalation or oxidative cyclization? mechanism of Pd-catalyzed annulation of enynones” Ni, H.; He, X.; Zhong, K.; Chen, H.; Lai, W.; Zhao, Z.; Zeng, Z.; Bai, R.*; Lan, Y.* Chem. Commun. 2021, 57, 8316-8319. (DOI: 10.1039/d1cc02744a)
(217) “Dehydrogenative 6π heterocyclization under visible light irradiation and mechanistic insights” Zhang, Z.; Chen, H.; Keller, N.; Xiong, Q.; Liu, L.; Lan, Y.*; Bein, T.*; Li, J.* Org. Chem. Front. 2021, 8, 3788-3795. (DOI: 10.1039/d1qo00356a)
(216) “Benzyne 1,2,4-Trisubstitution and Dearomative 1,2,4-Trifunctionalization” Shi, J.; Li, L.; Shan, C.; Chen, Z.; Dai, L.; Tan, M.; Lan, Y.*; Li, Y.* J. Am. Chem. Soc. 2021, 143, 10530-10536. (DOI: 10.1021/jacs.1c04389)
(215) “Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations” Qi, X.*; Lan, Y.* Acc. Chem. Res. 2021, 54, 2905-2915. (DOI: 10.1021/acs.accounts.1c00075)
(214) “Rhodium(II)-Catalyzed Regioselective Remote C−H Alkylation of Protic Indoles” Kong, L.; Han, X.; Chen, H.; Sun, H.; Lan, Y.*; Li, X.* ACS Catal. 2021, 11, 4929-4935. (DOI: 10.1021/acscatal.1c01052)
(213) “C(sp2)−X (X = Cl, Br, and I) Reductive Eliminations from Well-Defined Gold(III) Complexes: Concerted or Dissociation Pathways?” Kang, K.; Liu, S.; Xu, C.; Lu, Z.; Liu, S.; Leng, X.; Lan, Y.*; Shen ,Q.* Organometallics 2021, 40, 2231-2239. (DOI: 10.1021/acs.organomet.0c00784)
(212) “C(sp2)‑CF3 Reductive Elimination from Well-Defined Argentate(III) Complexes [nBu4N][Ag(Ar)(CF3)3]” Lu, Z.; Liu, S.; Lan, Y.*; Leng, X.; Shen, Q.* Organometallics 2021, 40, 1713-1718. (DOI: 10.1021/acs.organomet.1c00195)
(211) “Photoredox Catalysis Unlocks the Nickel-Catalyzed Cyanation of Aryl Halides under Benign Conditions” Jia, Y.; Liu, Y.-Y.; Lu, L.-Q.; Liu, S.-H.; Zhou, H.-B.; Lan, Y.*; Xiao, W.-J.* CCS Chem. 2021, 3, 2032-2041. (DOI: 10.31635/ccschem.021.202100934)
(210) “Atom Recombination of Difluorocarbene Enables 3-Fluorinated Oxindoles from 2-Aminoarylketones” Zhang, G.; Shi, Q.; Hou, M.; Yang, K.; Wang, S.; Wang, S.; Li, W.; Li, C.; Qiu, J.; Xu, H.; Zhou, L.; Wang, C.; Li, S.-J.; Lan, Y.*; Song, Q.* CCS Chem. 2021, 3, 1613-1621. (DOI: 10.31635/ccschem.021.202100979)
(209) “Mechanistic studies on nickel-catalyzed enantioselective [3 + 2] annulation for γ-butenolide synthesis via C-C activation of diarylcyclopropenones” Bai, D.*; Liu, S.; Chen, J.; Yu, Y.; Wang, M.; Chang, J.; Lan, Y.*; Li, X.* Org. Chem. Front. 2021, 8, 3023-3031. (DOI: 10.1039/D1QO00322D)
(208) “Tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer” Yang, Z.; Niu, Y.; He, X.; Chen, S.; Liu, S.; Li, Z.; Chen, X.; Zhang, Y.; Lan, Y.*; Shen, X.* Nat. Commun. 2021, 12, 2131. (DOI: 10.1038/s41467-021-22382-y)
(207) “Biomimetic Carbene Cascades Enabled Imine Derivative Migration from Carbene-Bearing Thiocarbamates” Li, X.; Chen, H.; Xuan, Q.; Ma, S.; Lan, Y.*; Song, Q.* Org. Lett. 2021, 23, 3518-3523. (DOI: 10.1021/acs.orglett.1c00930)
(206) “Oxidation of Pd(II) with disilane in a palladium-catalyzed disilylation of aryl halides: a theoretical view” Zhang, J.; Liu, S.; Zhang, T.; Liu, T.*; Lan, Y.* Dalton Trans. 2021, 49, 7656-7666. (DOI: 10.1039/d1dt00399b)
(205) “Metal-free C(sp3)–H functionalization of sulfonamides via strain-release rearrangement” Hu, J.*; Yang, X.; Shi, S.; Cheng, B.; Luo, X.*; Lan, Y.*; Loh, T.-P.* Chem. Sci. 2021, 12, 4034-4340. (DOI: 10.1039/d0sc06603f)
(204) “Theoretical Model for N‑Heterocyclic Carbene-Catalyzed Desymmetrizing [4 + 1] and [4 + 2] Annulations of an Enal and Aryldialdehyde with 1,3-Cyclopentenedione” Wang, X.; Li, S.-J.; Wang, Y.-N.; Wei, D.*; Lan, Y.* Org. Lett. 2021, 23, 2421-2425. (DOI: 10.1021/acs.orglett.1c00270)
(203) “Insights into the chiral sulfide/selenide-catalyzed electrophilic carbothiolation of alkynes: mechanism and origin of axial chirality” Zhang, Q.-Y.; Li, S.-J.; Wang, Y.; Song, J.; Lan, Y.*; Wei, D.* Org. Chem. Front. 2021, 8, 1983-1990. (DOI: 10.1039/d1qo00036e)
(202) “Ligand coordination- and dissociation induced divergent allylic alkylations using alkynes” Huang, Y.; Ma, C.; Liu, S.; Yang, L.-C.; Lan, Y.*; Zhao, Y.* Chem 2021, 7, 812-826. (DOI: 10.1016/j.chempr.2021.02.018)
(201) “On the mechanism of homogeneous Pt-catalysis: A theoretical view” Chen, H.; Li, Y.*; Liu, S.*; Xiong, Q.; Bai, R.; Wei, D.*; Lan, Y.* Coor. Chem. Rev. 2021, 437, 213863. (DOI: 10.1016/j.ccr.2021.213863)
(200) “Synergistic Dinuclear Rhodium Induced Rhodium-Walking Enabling Alkene Terminal Arylation: A Theoretical Study” Heng, D.; Chen, H.; He, X.; Liu, S.; Zhu, L.; Zhong, K.; Zhang, T.; Bai, R.*; Lan, Y.* ACS Catal. 2021, 11, 3975-3987. (DOI: 10.1021/acscatal.0c05554)
(199) “Desymmetrization of 1,3-Diones by Catalytic Enantioselective Condensation with Hydrazine” Yang, B.; Dai, J.; Luo, Y.; Lau, K. K.; Lan, Y.*; Shao, Z.*; Zhao, Y.* J. Am. Chem. Soc. 2021, 143, 4179-4186. (DOI: 10.1021/jacs.1c01366)
(198) “Multiple Functional Organocatalyst-Promoted Inert C–C Activation: Mechanism and Origin of Selectivities” Zhang, M.; Wang, Y.; Li, S.-J.; Wang, X.; Shi, Q.; Li, X.; Qu, L.-B.; Wei, D.*; Lan, Y.* ACS Catal. 2021, 11, 3443-3454. (DOI: 10.1021/acscatal.0c05511)
(197) “How Solvents Control the Chemoselectivity in Rh-Catalyzed Defluorinated [4 + 1] Annulation” Liu, S.; Zhu, L.; Zhang, T.; Zhong, K.; Li, S.-J.; Bai, R.*; Lan, Y.* Org. Lett. 2021, 23, 1489-1494. (DOI: 10.1021/acs.orglett.1c00223)
(196) “Catalytic Atroposelective Catellani Reaction Enables to Construct Axially Chiral Biaryl Monophosphine Oxides” Feng, Q.; Ma, X.; Bao, W.; Li, S.-J.; Lan, Y.*; Song, Q.* CCS Chem. 2021, 3, 377-387. (DOI: 10.31635/ccschem.021.202000725)
(195) “Aryne 1,2,3,5-Tetrasubstitution Enabled by 3‑Silylaryne and Allyl Sulfoxide via an Aromatic 1,3-Silyl Migration” Shi, J.; Li, L.; Shan, C.; Wang, J.; Chen, Z.; Gu, R.; He, J.; Tan, M.; Lan, Y.*; Li, Y.* J. Am. Chem. Soc. 2021, 143, 2178-2184. (DOI: 10.1021/jacs.0c11119)
(194) “Lewis acid–catalyzed domino generation/[2,3]-sigmatropic rearrangement of ammonium ylidesto access chiral azabicycles” Xi, S.; Dong, J.; Chen, H.; Dong, Q.; Yang, J.; Tan, Q.; Zhang, C.; Lan, Y.*; Zhang, M.* Sci. Adv. 2021, 7, eabd5290. (DOI: 10.1126/sciadv.abd5290)
(193) “Rhodium-Catalyzed Atroposelective Construction of Indoles via C-H Bond Activation” Sun, L.; Chen, H.; Liu, B.; Chang, J.; Kong, L.; Wang, F.*; Lan, Y.*; Li, X.* Angew. Chem. Int. Ed. 2021, 60, 8391-8395. (DOI: 10.1002/anie.202012932)
(192) “Predicting the origin of selectivity in NHCcatalyzed ring opening of formylcyclopropane: a theoretical investigation” Wang, Y.; Qiao, Y.; Lan, Y.*; Wei, D.* Catal. Sci. Tech. 2021, 11, 332-337. (DOI: 10.1039/d0cy01768j)
(191) “Is the reaction sequence in phosphine-catalyzed [8+2] cycloaddition controlled by electrophilicity?” Lin, W.-X.; Pei, Z.; Gong, C.; Mo, H.; Yang, K.; Qu, L.-B.; Wei, D.; Song, J.-S.*; Li, S.-J.*; Lan, Y.* Chem. Commun. 2021, 57, 761-764. (DOI: 10.1039/d0cc07370a)
(190) “Mechanistic insights into the rhodium-copper cascade catalyzed dual C-H annulation of indoles” He, X.; Zhu, L.; Heng, D.; Liu, F.; Liu, S.; Zhong, K.; Shan, C.*; Bai, R.*; Lan, Y.* Org. Chem. Front. 2020, 7, 1739-1746. (DOI: 10.1039/D0QO01332C)
(189) “Elemental sulfur enabled divergent synthesis of disulfides, diselenides and polythiophenes from β-CF3-1,3-enynes” Jin, S.; Li, S.-J.; Ma, X.; Su, J.; Chen, H.; Lan, Y.*; Song, Q.* Angew. Chem. Int. Ed. 2021, 60, 881-888. (DOI: 10.1002/anie.202009194)
(188) “Possible Mechanisms and Origin of Selectivities for Phosphine-Catalyzed [2+n] (n=3, 4) Annulations of Saturated Amines and δ-Acetoxy Allenoates” Yang, T.-T.; Wang, C.; Li, S.-J.; Zhang, M.; Wei, D.*; Lan, Y.* Asian J. Org. Chem. 2021, 10, 619-625. (DOI: 10.1002/ajoc.202000679)
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(109) “Mechanistic Insights into Manganese(I)-Catalyzed Chemoselective Hydroarylations of Alkynes: A Theoretical Study” Wang, Z.; Zhu, L.; Zhong, K.; Qu, L.-B.; Bai, R.*; Lan, Y.* ChemCatChem 2018, 10, 5820-5826. (DOI: 10.1002/cctc.201801301)
(108) “Retro-metal-ene versus retro-Aldol: Mechanistic insight into Rh-catalysed formal [3+2] cycloaddition” Liu, S.; Zhang, T.; Zhu, L.; Zhong, K.; Gong, J.; Yang, Z.*; Bai, R.*; Lan, Y.* Chem. Commun. 2018, 13551-13554. (DOI: 10.1039/C8CC08335E)
(107) “Difluoromethylated Organogold(III) Complex cis-[Au(PCy3)(4-F-C6H4)(CF2H)(Cl)]: Preparation, Characterization and its C(sp2)−CF2H Reductive Elimination” Liu, S.; Kang, K.; Liu, S.; Wang, D.; Wei, P.*; Lan, Y.*; Shen, Q.* Organometallics 2018, 36, 3901-3908. (DOI: 10.1021/acs.organomet.8b00579)
(106) “Long Distance Unconjugated Agostic-Assisted 1,5-H Shift in a Rumediated Alder-Ene Type Reaction: Mechanism and Stereoselectivity” Shan, C.; Zhong, K.; Qi, X.; Xu, D.; Qu, L.-B.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 3178-3185. (DOI: 10.1039/C8QO00699G)
(105) “Base-catalyzed Borylation/B-O Elimination of Propynols and B2pin2 Delivering Tetrasubstituted Alkenylboronates” Kuang, Z.; Chen, H.; Yan, J.; Yang, K.; Lan, Y.*; Song, Q.* Org. Lett. 2018, 29, 5153-5157. (DOI: 10.1021/acs.orglett.8b02077)
(104) “Mechanistic View of Ru-Catalyzed C–H Bond Activation and Functionalization: Computational Advances” Shan, C.; Zhu, L.; Qu, L.-B.; Bai, R.*; Lan, Y.* Chem. Soc. Rev. 2018, 47, 7552-7576. (DOI: 10.1039/c8cs00036k)
(103) “Toward a Predictive Understandings of Phosphine-Catalyzed [3+2] Annulation of Allenoates with Acrylate or Imine” Yu, Z.; Jin, Z.; Duan, M.; Bai, R.*; Lu, Y.*; Lan, Y.* J. Org. Chem. 2018, 83, 9729-9740. (DOI: 10.1021/acs.joc.8b01259)
(102) “One-pot synthesis of β-lactams by the Ugi and Michael addition cascade reaction” Gao, X.; Shan, C.; Chen, Z.; Liu, Y.; Zhao, X.; Zhang, A.; Yu, P.; Galons, H.*; Lan, Y.*; Lu, K.* Org. Biomol. Chem. 2018, 16, 6096-6105. (DOI: 10.1039/c8ob01176a)
(101) “Editorial: Introduction to the special column on organocatalysis” Lan, Y.*; Liu, X.* Chin. Chem. Lett. 2018, 29, 1179-1180. (DOI: 10.1016/j.cclet.2018.07.009)
(100) “Experimental and Theoretical Studies on Ru(II)-Catalyzed Oxidative C−H/C−H Coupling of Phenols with Aromatic Amides Using Air as Oxidant: Scope, Synthetic Applications and Mechanistic Insights” Zhang, L.; Zhu, L.; Zhang, Y.; Yang, Y.; Wu, Y.; Ma, W.; Lan, Y.*; You, J.* ACS Catal. 2018, 8, 8324-8335. (DOI: 10.1021/acscatal.8b02816)
(99) “C6-Selective Direct Arylation of 2-Phenylpyridine via an Activated N-methylpyridinium Salt: A Combined Experimental and Theoretical Study” Yin, C.; Zhong, K.; Li, W.; Yang, X.; Sun, R.; Zhang, C.; Zheng, X.; Yuan, M.; Li, R.; Lan, Y.*; Fu, H.*; Chen, H.* Adv. Synth. Catal. 2018, 360, 3990-3998. (DOI: 10.1002/adsc.201800666)
(98) “Mechanism investigation for anoin-assisted nickel catalyzed C–F bond functionalization reaction: a DFT study” Zeng, Z.; Zhang, T.; Yue, X.; Zhang, H.*; Bai, R.*; Lan, Y.* Sci. Sin. Chem. 2018, 48, 736-742. (DOI: 10.1360/N032018-00105)
(97) “Catalytic Lactonization of Unactivated Aryl C−H Bonds with CO2: Experimental and Computational Investigation” Song, L.; Zhu, L.; Zhang, Z.; Ye, J.-H.; Yan, S.-S.; Han, J.-L.; Yin, Z.-B.; Lan, Y.*; Yu, D.-G.* Org. Lett. 2018, 20, 3776-3779.(DOI: 10.1021/acs.orglett.8b01363)
(96) “Recent Advances in Alkaline-Earth-Metal-Catalyzed Hydrofunctionalization Reactions” Li, Y.; Cheng, Y.; Shan, C.; Zhang, J.; Xu, D.; Bai, R.; Qu, L.; Lan, Y.* Chin. J. Org. Chem. 2018, 38, 1885-1896. (DOI: 10.6023/cjoc201804031)
(95) “Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO2” Yan, S.-S.; Zhu, L.; Ye, J.-H.; Zhang, Z.; Huang, H.; Zeng, H.; Li, C.-J.*; Lan, Y.*; Yu, D.-G.* Chem. Sci. 2018, 9, 4873-4878. (DOI: 10.1039/c8sc01299g)
(94) “Author Profile” Lan, Yu* Angew. Chem. Int. Ed. 2018, 57, 11852. (DOI: 10.1002/anie.201804435)
(93) “Redox-Neutral Access to Isoquinolinones via Rhodium(III)-Catalyzed Annulations of O‑Pivaloyl Oximes with Ketenes” Yang, X.; Liu, S.; Yu, S.; Kong, L.; Lan, Y.*; Li, X.* Org. Lett. 2018, 20, 2698-2701. (DOI: 10.1021/acs.orglett.8b00906)
(92) “Ruthenium(II)-enabled para-selective C–H difluoromethylation of anilides and their derivatives” Yuan, C.; Zhu, L.; Chen, C.; Chen, X.; Yang, Y.; Lan, Y.*; Zhao, Y.* Nat. Commun. 2018, 9, 1189. (DOI: 10.1038/s41467-018-03341-6)
(91) “Aryne Trifunctionalization Enabled by 3-Silylaryne as 1,2-Benzdiyne Equivalent” Lv, C.; Wan, C.; Liu, S.; Lan, Y.*; Li, Y.* Org. Lett. 2018, 20, 1919-1923. (DOI: 10.1021/acs.orglett.8b00469)
(90) “Counterion Effect and Directing Group Effect in Rh-Mediated C-H Bond Activation Processes: A Theoretical Study” Luo, Y.; Liu, S.; Xu, D.; Qu, L.-B.; Luo, X.*; Bai, R.*; Lan, Y.* J. Organomet. Chem. 2018, 862, 148-153. (DOI: 10.1016/j.jorganchem.2018.03.016)
(89) “Mechanistic Insight Into Cobalt-Catalyzed Stereodivergent Semihydrogenation of Alkynes: The Story of Selectivity Control” Qi, X.; Liu, X.; Qu, L.-B.; Liu, Q.*; Lan, Y.* J. Catal. 2018, 362, 25-34. (DOI: 10.1016/j.jcat.2018.03.016)
(88) “Theoretical insight into phosphoric acid-catalyzed asymmetric conjugate addition of indolizines to α,β-unsaturated ketones” Chen, H.; Zhu, L.; Zhong, K.; Yue, X.; Qu, L.-B.; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2018, 29, 1237-1241. (DOI: 10.1016/j.cclet.2018.03.018)
(87) “Mechanism of phosphinecatalyzed allene coupling reactions: advances in theoretical investigations” Cui, C.-X.; Shan, C.; Zhang, Y.-P.; Chen, X.-L.; Qu, L.-B.*; Lan, Y.* Chem. Asian J. 2018, 13, 1076-1088. (DOI: 10.1002/asia.201800146)
(86) “Ni-Catalyzed C–F Bond Functionalization of Unactivated Aryl Fluorides and Corresponding Coupling with Oxazoles” Yin, Y.; Yue, X.; Zhong, Q.; Jiang, H.; Bai, R.*; Lan, Y.*; Zhang, H. Adv. Synth. Catal. 2018, 360, 1639-1643. (DOI: 10.1002/adsc.201701506)
(85) “C–H bond Cleavage Occurring on a Rh(V) Intermediate: a Theoretical Study of Rh-Catalyzed Arene Azidation” Liu, S.; Qi, X.; Qu, L.-B.; Bai, R.*; Lan, Y.* Catal. Sci. Tech. 2018, 8, 1645-1651. (DOI: 10.1039/c7cy02367g)
(84) “Regioselective Palladium-Catalyzed C‑H Bond Trifluoroethylation of Indoles: Exploration and Mechanistic Insight” Zhang, H.; Wang, H.-Y.; Luo, Y.; Chen, C.; Cao, Y.; Chen, P.; Guo, Y.-L.; Lan, Y.*; Liu, G.* ACS Catal. 2018, 8, 2173-2180. (DOI: 10.1021/acscatal.7b03220)
(83) “Palladium-Catalyzed Intermolecular Ditrifluoromethoxylation of Unactivated Alkenes: CF3O- Palladation Initiated by Pd(IV)” Chen, C.; Luo, Y.; Fu, L.; Chen, P.; Lan, Y.*; Liu, G.* J. Am. Chem. Soc. 2018, 140, 1207-1210. (DOI: 10.1021/jacs.7b11470)
(82) “Insights of Disilylation and Distannation: Sequence Influence and Ligand/Steric Effect in Pd-Catalyzed Difunctionalization of Carbenes” Yue, X.; Shan, C.; Qi, X.; Luo, X.; Zhu, L.; Zhang, T.; Li, Y.; Li, Y.; Bai, R.*; Lan, Y.* Dalton Trans. 2018, 46, 1819-1826. (DOI: 10.1039/C7DT04084A)
(81) “Ruthenium(II)-catalyzed C-H Difluoromethylation of Ketoxime: Tuning the Regioselectivity from meta to para Position” Yuan, C.; Zhu, L.; Zeng, R.; Lan, Y.*; Zhao, Y.* Angew. Chem. Int. Ed. 2018, 57, 1277-1281. (DOI: 10.1002/anie.201711221)
(80) “On the Mechanism of Copper-Catalyzed Oxytrifluoromethylation of Allylamines with CO2: A Computational Study” Zhu, L.; Ye, J.-H.; Duan, M.; Qi, X.; Yu, D.-G.*; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 633-639. (DOI: 10.1039/C7QO00838D)
(79) “Ni(I)–Ni(III) vs Ni(II)–Ni(IV): Mechanistic Study of Ni-catalyzed Alkylation of Benzamides with Alkyl Halides” Li, Y.; Zou, L.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2018, 4, 615-622. (DOI: 10.1039/C7QO00850C)
(78) “C(sp2)-C(sp2) Reductive Elimination from Well-Defined Diarylgold(III) Complexes” Kang, K.; Liu, S.; Xu, T.; Wang, D.; Leng, X.; Bai, R.; Lan, Y.*; Shen, Q.* Organometallics 2017, 35, 4727-4740. (DOI: 10.1021/acs.organomet.7b00588)
(77) “Reactivity and regioselectivity in Diels–Alder reactions of anion encapsulated fullerenes” Cui, C.-X.; Zhang, Z.-P.; Zhu, L.; Qu, L.-B.; Zhang, Y.-P.; Lan, Y.* Phys. Chem. Chem. Phys. 2017, 42, 30393-30401. (DOI: 10.1039/C7CP06365B)
(76) “Mechanism of Rhodium-Catalyzed C−H Functionalization: Advances in Theoretical Investigation” Qi, X.; Li, Y.; Bai, R.; Lan, Y.* Acc. Chem. Res. 2017, 50, 2799-2808. (DOI: 10.1021/acs.accounts.7b00400)
(75) “Radical Trifluoromethylative Dearomatization of Indoles and Furans with CO2” Ye. J.-H.; Zhu, L.; Yan, S.-S.; Miao, M.; Zhang, X.-C.; Zhou, W.-J.; Li, J.; Lan, Y.*; Yu, D.-G.* ACS Catal. 2017, 7, 8324-8330. (DOI: 10.1021/acscatal.7b02533)
(74) “Rhodium/Copper Cocatalyzed Highly trans-Selective 1,2- Diheteroarylation of Alkynes with Azoles via C−H Addition/Oxidative Cross-Coupling: A Combined Experimental and Theoretical Study” Tan, G.; Zhu, L.; Liao, X.; Lan, Y.*; You, J.* J. Am. Chem. Soc. 2017, 139, 15724-15737. (DOI: 10.1021/jacs.7b07242)
(73) “Nine-Membered Benzofuran-Fused Heterocycles: Enantioselective Synthesis by Pd-Catalysis and Rearrangement via Transannular Bond Formation” Rong, Z.-Q.; Yang, L.-C.; Liu, S.; Yu, Z.; Wang, Y.-N.; Tan, Z. Y.; Huang, R.-Z.; Lan, Y.*; Zhao, Y.* J. Am. Chem. Soc. 2017, 139, 15304-15307. (DOI: 10.1021/jacs.7b09161)
(72) “Mechanistic Study on the Fluoride-induced Activation of Kobayashi Precursor: pseudo-SN2 Pathway via a PentaCoordinated Silicon ate-Complex” Liu, S.; Li, Y.*; Lan, Y.* Eur. J. Org. Chem. 2017, 42, 6349-6353. (DOI: 10.1002/ejoc.201701249)
(71) “Cp*CoIII-Catalyzed Branch-Selective Hydroarylation of Alkynes via C−H Activation: Efficient Access to α-gem-Vinylindoles” Zhou, X.; Luo, Y.; Kong, L.; Xu, Y.; Zheng, G.; Lan, Y.*; Li, X.* ACS Catal. 2017, 7, 7296-7304. (DOI: 10.1021/acscatal.7b02248)
(70) “Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study” Xu, D.; Shan, C.; Li, Y.; Qi, X.; Luo, X.*; Bai, R.*; Lan, Y.* Inorg. Chem. Front. 2017, 4, 1813. (DOI: 10.1039/c7qi00459a)
(69) “From Mechanistic Study to Chiral Catalyst Optimization: Theoretical Insight into Binaphthophosphepine-catalyzed Asymmetric Intramolecular [3+2] Cycloaddition” Duan, M.; Zhu, L.; Qi, X.; Yu, Z.; Li, Y.; Bai, R.*; Lan, Y.* Sci. Rep. 2017, 7, 7619. ( DOI:10.1038/s41598-017-07863-9)
(68) “Catalyst-controlled regioselectivity in phosphine catalysis: the synthesis of spirocyclic benzofuranones via regiodivergent [3+2] annulations of aurones and an allenoate” Ni, H.; Yu, Z.; Yao, W.; Lan, Y.*; Ullah, N.*; Lu, Y.* Chem. Sci. 2017, 8, 5699-5704. (DOI: 10.1039/c7sc02176c)
(67) “Mechanistic insights into copper-catalyzed trifluoromethylation of aryl boronic acids: a theretical study.” He, X.; Shan, C.; Qi, X.*; Bai, R.*; Lan, Y.* Sci. Sin. Chem. 2017, 47, 859-864. (DOI: 10.1360/N032017-00056)
(66) “Ir(III)/Ir(V) or Ir(I)/Ir(III) Catalytic Cycle? Steric-Effect-Controlled Mechanism for the para-C−H Borylation of Arenes” Zhu, L.; Qi, X.; Li, Y.; Duan, M.; Zou, L.; Bai, R.*; Lan, Y.* Organometallics 2017, 36, 2107-2115. (DOI: 10.1021/acs.organomet.7b00151)
(65) “Chiral phosphine-mediated intramolecular [3+2] annulation: enhanced enantioselectivity by achiral Brønsted acid” Yao, W.; Yu, Z.; Wen, S.; Ni, H.; Ullah, N.*; Lan, Y.*; Lu, Y.* Chem. Sci. 2017, 8, 5196-5200. (DOI: 10.1039/c7sc00952f)
(64) “Enantioselective alkynylation of N-sulfonyl -ketiminoesters via a Friedel–Crafts alkylation strategy” Liu, R.-R.; Zhu, L.; Hu, J.-P.; Lu, C.-J.; Gao, J.-R.; Lan, Y.*; Jia, Y.-X.* Chem. Commun. 2017, 52, 5890-5893. (DOI: 10.1039/c7cc01015j)
(63) “Bioinspired Total Synthesis of Homodimericin A” Huang, J.; Gu, Y.; Guo, K.; Zhu, L.; Lan, Y.*; Gong, J.*; Yang, Z.* Angew. Chem. Int. Ed. 2017, 56, 7890-7894. ( DOI: 10.1002/anie.201702768)
(62) “Mechanism, Regio-, and Diastereoselectivity of Rh(III)-Catalyzed Cyclization Reactions of N‑Arylnitrones with Alkynes: A Density Functional Theory Study” Li, Y.; Shan, C.; Yang, Y.-F.; Shi, F.; Qi, X.; Houk, K. N.*; Lan, Y.* J. Phys. Chem. A 2017, 121, 4496-4504. ( DOI: 10.1021/acs.jpca.7b01020)
(61) “Bioinspired Asymmetric Synthesis of Hispidanin A” Li, F.; Tu, Q.; Chen, S.; Zhu, L.; Lan, Y.*; Gong, J.*; Yang, Z.* Angew. Chem. Int. Ed. 2017, 56, 5844-5848. (DOI: 0.1002/anie.201700838)
(60) “C−O Functionalization of α‑Oxyboronates: A Deoxygenative gemDiborylation and gem-Silylborylation of Aldehydes and Ketones” Wang, L.; Zhang, T.; Sun, W.; He, Z.; Xia, C.; Lan, Y.*; Liu, C.* J. Am. Chem. Soc. 2017, 139, 5257-5264. (DOI: 10.1021/jacs.7b02518)
(59) “Mononuclear or Dinuclear? Mechanistic Study of the ZincCatalyzed Oxidative Coupling of Aldehydes and Acetylenes” Yue, X.; Qi, X.; Bai, R.; Lei, A.*; Lan, Y.* Chem. Eur. J. 2017, 23, 6419-6425. (DOI: 10.1002/chem.201700733)
(58) “Mechanism of Alkaline Earth Metal Catalyzed Hydroboration of Carbodiimides: A Theoretical Study” Xu, D.; Shan, C.; Bai, R.*; Lan, Y.* Chin. J. Org. Chem. 2017, 37, 1231-1236. (DOI: 10.6023/cjoc201701033)
(57) “Regioselective -Addition of Deconjugated Butenolides: Enantioselective Synthesis of Dihydrocoumarins” Wu, B.; Yu, Z.; Gao, X.; Lan, Y.*; Zhou, Y.* Angew. Chem. Int. Ed. 2017, 56, 4006-4010. (DOI:10.1002/anie.201700437)
(56) “Stabilization of Two Radicals with One Metal: A Stepwise Coupling Model for Copper-Catalyzed Radical–Radical Cross-Coupling” Qi, X.; Zhu, L.; Bai, R.*; Lan, Y.* Sci. Rep. 2017, 7, 43579. (DOI: 10.1038/srep43579)
(55) “Thiolate–palladium(IV) or sulfonium–palladate(0)? A theoretical study on the mechanism of palladium-catalyzed C–S bond formation reactions” Xu, D.; Qi, X.; Duan, M.; Yu, Z.; Zhu, L.; Shan, C.; Yue, X.; Bai, R.*; Lan, Y.* Org. Chem. Front. 2017, 4, 943-950. (DOI: 10.1039/c6qo00841k)
(54) “Room-Temperature Coupling/Decarboxylation Reaction of α‑Oxocarboxylates with α‑Bromoketones: Solvent-Controlled Regioselectivity for 1,2- and 1,3-Diketones” He, Z.; Qi, X.; She, Z.; Zhao, Y.; Li, S.; Tang, J.; Gao, G.*; Lan, Y.*; You, J.* J. Org. Chem. 2017, 82, 1403-1411. (DOI: 10.1021/acs.joc.6b02575)
(53) “Application of Gausian Software in Organic Chemistry Teaching in Senior High School” Li, Y.;* Qi, X.; Lan, Y.* Chin. J. Chem. Edu. 2017, 38(13), 43. (DOI: 10.13884/J.1003-3807hxjy.2016120022)
(52) “Biomimetically inspired asymmetric total synthesis of (+)-19-dehydroxyl arisandilactone A” Han, Y.; Jiang, Y.; Li, Y.; Yu, H.; Tong, B.; Niu, Z.; Zhou, S.; Liu, S.; Lan, Y.;* Chen, J.;* Yang, Z.;* Nat. Commun. 2017, 8, 14233. (DOI: 10.1038/ncomms14233)
(51) “Ligand effect on nickle-catalyzed reductive alkyne-aldehyde coupling reactions: a computational study. ” Luo, X.; Li, Y.; Qi, X.; Zhu, L.; Chen, C.;* Lan, Y.* Sci. Sin. Chem. 2017, 47, 341-349. (DOI:10.1360/N032016-00129)
(50) “Computational Investigation of the Role Played by Rhodium(V) in the Rhodium(III)-Catalyzed ortho-Bromination of Arenes” Zhang, T.; Qi, X.; Liu, S.; Bai, R.; * Liu, C.; * Lan, Y.* Chem.-Eur. J. 2017, 23, 2690-2699. (DOI: 10.1002/chem.201605188)
(49) “Readily Accessible and Highly Efficient Ferrocene-Based AminoPhosphine-Alcohol (f-Amphol) Ligands for Iridium-Catalyzed Asymmetric Hydrogenation of Simple Ketones” Yu, J.; Duan, M.; Wu, W.;Qi, X. ; Xue, P.; Lan, Y.;* Dong, X-Q.;* Zhang, X.;* Chem.-Eur. J. 2017, 23, 970-975. (DOI: 10.1002/chem.201604855)
(48) “C8–H bond activation vs. C2–H bond activation: from naphthyl amines to lactams” Shi, R.; Lu, L.; Xie, H.; Yan, J.; Xu, T.; Zhang, H.; Qi, X.; Lan, Y.*; Lei, A.* Chem. Commun. 2016, 52, 13307. (DOI: 10.1039/c6cc06358f)
(47) “Mild Acylation of C(sp3)−H and C(sp2)−H Bonds under Redox-Neutral Rh(III) Catalysis” Yu, S.; Li, Y.; Kong, L.; Zhou, X.; Tang, G.; Lan, Y.;* Li, X.* ACS Catal. 2016, 6, 7744-7748. (DOI: 10.1021/acscatal.6b02668)
(46) “Effective Chirality Transfer in [3+2] Reaction between AllenylRhodium and Enal: Mechanistic Study Based on DFT Calculations” Qi, X.; Liu, S.; Zhang, T.; Long, R.; Huang, J.; Gong, J.; Yang, Z.;* Lan, Y.* J. Org. Chem. 2016, 81, 8306-8311. (DOI: 10.1021/acs.joc.6b01429)
(45) “Asymmetric Transfer Hydrogenation of Imines using Alcohol: Efficiency and Selectivity are Influenced by the Hydrogen Donor” Pan, H. J.; Zhang, Y.; Shan, C.; Yu, Z.; Lan, Y.;* Zhao, Y.* Angew. Chem. Int. Ed. 2016, 55, 9615-9619. (DOI:10.1002/anie.201604025)
(44) “Reactivity of Single-Walled Carbon Nanotubes in the Diels–Alder Cycloaddition Reaction: Distortion–Interaction Analysis along the Reaction Pathway” Li, Y.; Osuna, S.; Garcia-Borràs, M.; Qi, X.; Liu, S.; Houk, K. N.;* Lan, Y.* Chem.-Eur. J. 2016, 22, 12819-12824. (DOI: 10.1002/chem.201601799)
(43) “Iridium Catalysts with f‑Amphox Ligands: Asymmetric Hydrogenation of Simple Ketones” Wu, W.; Liu, S.; Duan, M.; Tan, X.; Chen, C.; Xie, Y.; Lan, Y.;* Dong, X.-Q.; Zhang, X.* Org. Lett. 2016, 18, 2938-2941. (DOI: 10.1021/acs.orglett.6b01290)
(42) “Computational Studies on an Aminomethylation Precursor: (Xantphos)Pd(CH2NBn2)+” Qi, X.; Liu, S.; Lan, Y.* Organometallics 2016, 35, 1582-1585. (DOI: 10.1021/acs.organomet.6b00234)
(41) “Anthranil: An Aminating Reagent Leading to Bifunctionality for Both C(sp3)-H and C(sp2)-H under Rhodium(III) Catalysis” Yu, S.; Tang, G.; Li, Y.; Zhou, X.; Lan, Y.;* Li, X.* Angew. Chem. Int. Ed. 2016, 55, 8696-8700. (DOI: 10.1002/anie.201602224)
(40) “Efficient Synthesis of Dimeric Oxazoles, Piperidines and Tetrahydroisoquinolines from N-Substituted 2-Oxazolones” He, Y.;* Agarwal, P. K.; Kiran, I. N.; Yu, R.; Cao, B.; Zou, C.; Zhou, X.; Xu, H.; Xu, B.; Zhu, L.; Lan, Y.;* Nicolaou, K. C.* Chem.-Eur. J. 2016, 22, 7696-7701. (DOI: 10.1002/chem.201601471)
(39) “Regio- and Stereoselective Syntheses of 7-Oxabicyclo[2.2.1]heptanes via a Gold(I)-Catalyzed Cycloisomerization of Alkynediols: Asymmetric Total Synthesis of Farnesiferol C” Gu, Y.-Q.; Zhang, P.-P.; Fu, J.-K.; Liu, S.; Lan, Y.*; Gong, J.-X.*; Yang, Z.* Adv. Synth. Catal. 2016, 358, 1392-1397. (DOI: 10.1002/adsc.201600218)
(38) “Mechanism of Ruthenium-Catalyzed Direct Arylation of C−H Bonds in Aromatic Amides: A Computational Study” Shan, C.; Luo, X.; Qi, X.; Liu, S.; Li, Y.; Lan, Y.* Organometallics 2016, 35, 1440-1445. (DOI: 10.1021/acs.organomet.6b00064)
(37) “Rhodium-Catalyzed Cyclocarbonylation of Ketimines via C−H Bond Activation” Gao, B.; Liu, S.; Lan, Y.*; Huang, H.* Organometallics 2016, 35, 1480-1487. (DOI: 10.1021/acs.organomet.6b00072)
(36) “Mechanism of Rhodium-Catalyzed Formyl Activation: A Computational Study” Luo, X.; Bai, R.; Liu, S.; Shan, C.; Chen, C.; Lan, Y.* J. Org. Chem. 2016, 81, 2320-2326. (DOI: 10.1021/acs.joc.5b02828)
(35) “Mechanism and electronic effect for the synthesis of 6-aroylated phenanthridines: a theoretical study” Xu, T.; Qi, X.; Lan, Y.* Sci. Sin. Chem. 2016, 46, 616-622. (DOI: 10.1360/N032015-00217)
(34) “Rhodium-Catalyzed Hetero-(5+2) Cycloaddition of Vinylaziridines and Alkynes: A Theoretical View of the Mechanism and Chirality Transfer” Zhu, L.; Qi, X.; Lan, Y.* Organometallics 2016, 35, 771-777. (DOI: 10.1021/acs.organomet.6b00007)
(33) “Rhodium(III)-Catalyzed Annulation between N‑Sulfinyl Ketoimines and Activated Olefins: C−H Activation Assisted by an Oxidizing N−S Bond” Wang, Q.; Li, Y.; Qi, Z.; Xie, F.; Lan, Y.*; Li, X.* ACS Catal. 2016, 6, 1971-1980. (DOI: 10.1021/acscatal.5b02297)
(32) “Gold(I)-Catalyzed Angle Strain Controlled Strategy to Furopyran Derivatives from Propargyl Vinyl Ethers: Insight into the Regioselectivity of Cycloisomerization” Jin, S.; Jiang, C.; Peng, X.; Shan, C.; Cui, S.; Niu, Y.; Liu, Y.; Lan, Y.*; Liu, Y.*; Cheng, M.* Org. Lett. 2016, 18, 680-683. (DOI: 10.1021/acs.orglett.5b03641)
(31) “Mechanism of Synergistic Cu(II)/Cu(I)-Mediated Alkyne Coupling: Dinuclear 1,2-Reductive Elimination after Minimum Energy Crossing Point” Qi, X.; Bai, R.; Zhu, L.; Jin, R.; Lei, A.; Lan, Y.* J. Org. Chem. 2016, 81, 1654-1660. (DOI: 10.1021/acs.joc.5b02797)
(30) “Iron-Catalyzed Decarboxylative (4+1) Cycloadditions: Exploiting the Reactivity of Ambident Iron-Stabilized Intermediates” Wang, Q.; Qi, X.; Lu, L. Q.*; Li, T. R.; Yuan, Z. G.; Zhang, K.; Li, B. J.; Lan, Y.*; Xiao, W. J.* Angew. Chem. Int. Ed. 2016, 55, 2840-2844. (DOI: 10.1002/anie.201510413)
(29) “Regiodivergent Enantioselective γ‑Additions of Oxazolones to 2,3-Butadienoates Catalyzed by Phosphines: Synthesis of α,α-Disubstituted α‑Amino Acids and N,O‑Acetal Derivatives” Wang, T.; Yu, Z.; Hoon, D. L.; Phee, C. Y.; Lan, Y.*; Lu, Y.* J. Am. Chem. Soc. 2016, 138, 265-271. (DOI: 10.1021/jacs.5b10524)
(28) “Mechanism, chemoselectivity and enantioselectivity for the rhodium-catalyzed desymmetric synthesis of hydrobenzofurans: a theoretical study” Yu, Z.; Qi, X.; Li, Y.; Liu, S.; Lan, Y.* Org. Chem. Front. 2016, 3, 209-216. (DOI: 10.1039/c5qo00334b)
(27) “Copper-catalyzed aerobic oxidative coupling: From ketone and diamine to pyrazine” Wu, K.; Huang, Z.; Qi, X.; Li, Y.; Zhang, G.; Liu, C.; Yi, H.; Meng, L.; Bunel, E. E.; Miller, J. T.; Pao, C. W.; Lee, J. F.; Lan, Y.*; Lei, A.* Sci. Adv. 2015, 1, e1500656. (DOI: 10.1126/sciadv.1500656)
(26) “Silver Migration Facilitates Isocyanide-Alkyne [3+2] Cycloaddition Reactions: Combined Experimental and Theoretical Study” Qi, X.; Zhang, H.; Shao, A.; Zhu, L.; Xu, T.; Gao, M.*; Liu, C.*; Lan, Y.* ACS Catal. 2015, 5, 6640-6647. ( DOI: 10.1021/acscatal.5b02009)
(25) “Towards a general diastereoselective route to oxabicyclo[3.2.1]octanes via a gold-catalysed cascade reaction” Fu, J.; Gu, Y.; Yuan, H.; Luo, T.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Nat. Commun. 2015, 6, 8617. (DOI: 10.1038/ncomms9617)
(24) “Development of a Rhodium(II)-Catalyzed Chemoselective C(sp3)-H Oxygenation” Lin, Y.; Zhu, L.; Lan, Y.*; Rao, Y.* Chem.-Eur. J. 2015, 21, 14937-14942. (DOI: 10.1002/chem.201502140.)
(23) “Diastereoselective Synthesis of Cyclopentanoids: Applications to the Construction of the ABCD Tetracyclic Core of Retigeranic Acid” A Zhang, J.; Wang, X.; Li, S.; Li, D.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Chem.-Eur. J. 2015, 21, 12596-12600. (DOI: 10.1002/chem.201502423)
(22) “Distortion–interaction analysis along the reaction pathway to reveal the reactivity of the Alder-ene reaction of enes” Jin, R.; Liu, S.; Lan, Y.* RSC Adv. 2015, 5, 61426-61435. (DOI: 10.1039/c5ra10345b)
(21) “Highly enantioselective construction of tertiary thioethers and alcohols via phosphine-catalyzed asymmetric γ-addition reactions of 5H-thiazol-4-ones and 5H-oxazol-4-ones: scope and mechanistic understandings” Wang, T.; Yu, Z.; Hoon, D. L.; Huang, K.-W.; Lan, Y.*; Lu, Y.* Chem. Sci. 2015, 6, 4912-4922. (DOI: 10.1039/c5sc01614b)
(20) “Mechanism and selectivity for zinc-mediated cycloaddition of azides with alkynes: a computational study” Li, Y.; Qi, X.; Lei, Y.; Lan, Y.* RSC Adv. 2015, 5, 49802-49808. (DOI: 10.1039/c5ra02703a)
(19) “The Mechanism of N-O Bond Cleavage in Rhodium-Catalyzed C-H Bond Functionalization of Quinoline N-oxides with Alkynes:A Computational Study” Li, Y.; Liu, S.; Qi, Z.; Qi, X.; Li, X.*; Lan, Y.* Chem.-Eur. J. 2015, 21, 10131-10137. (DOI: 10.1002/chem.201500290)
(18) “Dinuclear versus mononuclear pathways in zinc mediated nucleophilic addition: a combined experimental and DFT study” Qi, X.; Li, Y.; Zhang, G.; Li, Y.; Lei, A.*; Liu, C.*; Lan, Y.* Dalton Trans. 2015, 44, 11165-11171. (DOI: 10.1039/c5dt01366f)
(17) “Tuning radical reactivity using iodine in oxidative C(sp3)–H/C(sp)–H cross-coupling: an easy way toward the synthesis of furans and indolizines” Tang, S.; Liu, K.; Long, Y.; Qi, X.; Lan, Y.*; Lei, A.* Chem. Commun. 2015, 51, 8769-8772. (DOI: 10.1039/c5cc01825k)
(16) “Nickel-Catalyzed Selective Oxidative Radical Cross-Coupling: An Effective Strategy for Inert Csp3−H Functionalization” Liu, D.; Li, Y.; Qi, X.; Liu, C.; Lan, Y.*; Lei, A.* Org. Lett. 2015, 17, 998-1001. (DOI: 10.1021/acs.orglett.5b00104)
(15) “Bimetallic zinc complex–active species in coupling of terminal alkynes with aldehydes via nucleophilic addition/Oppenauer oxidation” Yuan, J.; Wang, J.; Zhang, G.; Liu, C.; Qi, X.; Lan, Y.*; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lei, A.* Chem. Commun. 2015, 51, 576-579. (DOI: 10.1039/c4cc08152h)
(14) “Revealing the halide effect on the kinetics of the aerobic oxidation of Cu(I) to Cu(II)” Deng, Y.; Zhang, G.; Qi, X.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.*; Lei, A.* Chem. Commun. 2015, 51, 318-321. (DOI: 10.1039/c4cc05720a)
(13) “Transition-Metal-Free Formal Decarboxylative Coupling of a-Oxocarboxylates with a-Bromoketones under Neutral Conditions: A Simple Access to 1,3-Diketones” He, Z.; Qi, X.; Li, S.; Zhao, Y.; Gao, G.*; Lan, Y.*; Wu, Y.; Lan, J.; You, J.* Angew. Chem. Int. Ed. 2015, 54, 855-859. (DOI: 10.1002/anie.201409361)
(12) “Rhodium-Catalyzed C−H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C−N Bond: A Combination of Experimental and Theoretical Studies” Yu, S.; Liu, S.; Lan, Y.*; Wan, B.*; Li, X.* J. Am. Chem. Soc. 2015, 137, 1623-1631. (DOI: 10.1021/ja511796h)
(11) “Transition-Metal-Assisted Radical/Radical Cross-Coupling: A New Strategy to the Oxidative C(sp3)−H/N−H Cross-Coupling” Zhou, L.; Tang, S.; Qi, X.; Lin, C.; Liu, K.; Liu, C.; Lan, Y.*; Lei, A.* Org. Lett. 2014, 16, 3404-3407. (DOI: 10.1021/ol501485f)
(10) “Carbon-Centered Radical Addition to O=C of Amides or Esters as a Route to CO Bond Formations” Liu, D.; Tang, S.; Yi, H.; Liu, C.; Qi, X.; Lan, Y.*; Lei, A.* Chem.-Eur. J. 2014, 20, 15605-15610. (DOI: 10.1002/chem.201404607)
(9) “Chemoselective Carbophilic Addition of a-Diazoesters through Ligand-Controlled Gold Catalysis” Xi, Y.; Su, Y.; Yu, Z.; Dong, B.; McClain, E. J.; Lan, Y.*; Shi, X.* Angew. Chem. Int. Ed. 2014, 53, 9817-9821. (DOI: 10.1002/anie.201404946)
(8) “Visible-Light-Mediated Decarboxylation/Oxidative Amidation of α-Keto Acids with Amines under Mild Reaction Conditions Using O2” Liu, J.; Liu, Q.; Yi, H.; Qin, C.; Bai, R.; Qi, X.; Lan, Y.*; Lei, A.* Angew. Chem. Int. Ed. 2014, 53, 502-506. (DOI: 10.1002/anie.201308614)
(7) “Cu(II)−Cu(I) Synergistic Cooperation to Lead the Alkyne C−H Activation” Bai, R.; Zhang, G.; Yi, H.; Huang, Z.; Qi, X.; Liu, C.; Miller, J. T.; Kropf, A. J.; Bunel, E. E.; Lan, Y.*; Lei, A.* J. Am. Chem. Soc. 2014, 136, 16760-16763. (DOI: 10.1021/ja5097489)
(6) “Asymmetric total synthesis of (-)-lingzhiol via a Rh-catalysed [3+2] cycloaddition” Long, R.; Huang, J.; Shao, W.; Liu, S.; Lan, Y.*; Gong, J.*; Yang, Z.* Nat. Commun. 2014, 5, 5707. (DOI: 10.1038/ncomms6707)
(5) “Theoretical study of the electron-donating effects of thiourea ligands in catalysis” Liu, S.; Lei, Y.; Yang, Z.*; Lan, Y.* J. Mol. Struct. 2014, 1074, 527-533. (DOI:10.1016/j.molstruc.2014.06.034)
(4) “Hexahapto-chromium complexes of graphene: a theoretical study” Liu, S.; Lei, Y.; Li, Y.; Zhang, T.; Wang, H.; Lan, Y.* RSC Adv. 2014, 4, 28640. (DOI: 10.1039/c4ra03702b)
(3) “What Controls Stereoselectivity and Reactivity in the Synthesis of a trans-Decalin with a Quaternary Chiral Center via the Intramolecular Pauson−Khand Reaction: A Theoretical Study” Liu, S.; Shen, H.; Yu, Z.; Shi, L.; Yang, Z.*; Lan, Y.* Organometallics 2014, 33, 6282-6285. (DOI: 10.1021/om500840q )
(2) “Reactivity for the Diels−Alder Reaction of Cumulenes: A Distortion-Interaction Analysis along the Reaction Pathway” Liu, S.; Lei, Y.; Qi, X.; Lan, Y.* J. Phys. Chem. A 2014, 118, 2638-2645. (DOI: 10.1021/jp411914u)
(1) “Mechanism of Rhodium-Catalyzed Carbon−Silicon Bond Cleavage for the Synthesis of Benzosilole Derivatives: A Computational Study” Yu, Z.; Lan, Y.* J. Org. Chem. 2013, 78, 11501-11507. (DOI: 10.1021/jo402070f)
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